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Preheat oven to 350°F. In a large covered saucepan, cook sliced potatoes in a small amount of boiling, lightly salted water for about 10 minutes or just until tender, adding leek for the last 5 minutes of cooking. Drain potato mixture.
Coat a 2-quart rectangular baking dish with cooking spray. Place potato mixture in the bottom of the prepared baking dish. Sprinkle with the ham and cheese.
In a medium bowl, stir the milk into the flour until smooth. Stir in the egg, thyme and pepper. Pour the egg mixture over potato mixture.
Bake for 35 to 40 minutes or until a knife inserted near the center comes out clean. Serve immediately.