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Preheat oven to 250°F. Line a large rimmed baking sheet with parchment paper or foil; set aside.
In a large bowl, combine sugar, oil, chipotle, chili powder and five-spice powder. Add peanuts; toss gently to coat.
Spread peanuts in an even layer in the prepared baking pan. Bake for 30 minutes, stirring twice. Cool in pan on a wire rack.