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Preheat oven to 425°F. Place a baking sheet in the oven to preheat.
Cut each sweet potato lengthwise into 8 wedges (16 wedges total). In a large bowl drizzle sweet potato wedges with olive oil; toss until coated. In a small bowl stir together brown sugar, kosher salt, smoked paprika, pepper, pumpkin pie spice, and chili powder. Sprinkle spice mixture over sweet potatoes; toss to coat.
Arrange wedges in a single layer on the hot baking sheet. Roast 25 to 30 minutes or until tender and browned, turning wedges once halfway through roasting time.