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Preheat broiler. Brush both sides of chicken with pesto; arrange chicken on one side of the unheated rack of a broiler pan. Broil 4 inches from heat for 5 minutes. Turn chicken.
Meanwhile, cut zucchini (or squash) lengthwise into 1/4-inch-thick slices. Brush both sides of slices with half of the oil and sprinkle with salt and pepper. Arrange in a single layer on rack next to chicken.
Broil for 5 to 8 minutes more or until chicken is done (170°F) and zucchini is tender, turning zucchini once. Transfer chicken and zucchini to a serving platter; cover to keep warm.
Brush cut sides of bread with the remaining oil. Sprinkle with Parmesan. Place bread, cut-sides up, on rack of broiler pan. Broil 4 inches from heat for 1 to 2 minutes or until toasted. Cut bread crosswise into slices and serve with chicken and zucchini.