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In a medium heavy saucepan combine brown sugar and cocoa powder. Stir in bittersweet chocolate, butter, and buttermilk. Cook and stir over medium heat until chocolate and butter are melted and mixture is smooth.
Stir in whipping cream and corn syrup. Cook and stir over medium heat for 4 to 6 minutes or just until mixture is bubbly around the edges. Remove from heat; stir in vanilla. Serve warm over ice cream or cake.